The interest in block copolymers containing liquid crystalline (LC) se
gments is due to the resulting interplay between mesophase formation a
nd the microphase structure which creates opportunities in tailoring t
heir nanostructure. This review summarizes recent literature reporting
LC-coil block copolymers with well controlled microphase morphologies
produced using living methods. Developing applications are also descr
ibed and include LC displays and low energy surfaces.