A CIS-OCTAHEDRAL DICHLORO COMPLEX OF FE-III WITH A TETRADENTATE DIPYRIDYL-DIAMINO LIGAND

Authors
ALCOCK NW RYBAKAKIMOVA EV BUSCH DH
Citation
Nw. Alcock et al., A CIS-OCTAHEDRAL DICHLORO COMPLEX OF FE-III WITH A TETRADENTATE DIPYRIDYL-DIAMINO LIGAND, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 1385-1387
Citations number
18
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
10
Pages
1385 - 1387
Database
ISI
SICI code
0108-2701(1997)53:<1385:ACDCOF>2.0.ZU;2-6
Abstract
In [N,N'-bis(2-pyridylmethyl)-1, 3-propanediamine-N,N',N '',N''']dichl oroiron(III) perchlorate, [FeCl2(C15H20N4)]ClO4, the linear tetradenta te Ligand adopts the cis-beta configuration which provides a favourabl e geometry for the six-membered chelate ring. The Fe-N distances show lengthening from the trans influence of the chloride ligands, with Fe- N-py values of 2.152 (3) and 2.179 (3) Angstrom, and Fe-N-amine distan ces of 2.141 (4) and 2.178 (4) Angstrom.