A. Pal et M. Bandyopadhyay, FLUOROMETRIC-DETERMINATION OF TRICHLOROACETIC-ACID AND ITS APPLICATION IN WATER SAMPLE ANALYSIS, INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 4(5), 1997, pp. 253-255
A simple and rapid method for the determination of trichloroacetic aci
d (TCA) at the parts per million (ppm) level is developed. This is bas
ed on the photoreaction of TCA with diphenylamine (DPA) to give a fluo
rescent product (lambda(cm): 380 nm. lambda(exc): 335 nm). The method
has excellent reproducibility. The linear dynamic range for TCA is 20-
200 ppm Effects of reagent concentration, irradiation time and solvent
are studied. The method is applicable to water analysis.