A. Usui et al., MANGANESE MICROCHIMNEYS BURIED IN THE CENTRAL PACIFIC PELAGIC SEDIMENTS - EVIDENCE OF INTRAPLATE WATER CIRCULATION, Marine geology, 141(1-4), 1997, pp. 269-285
Manganese oxide deposits of an irregular tube-like shape with unique c
omposition and structure were found within Pliocene siliceous sediment
s from an abyssal hill in the Central Pacific manganese nodule provinc
e. Effective separation of Mn from Fe and probably a rapid rate of Mn
deposition are suggested from the chemical composition: a very high Mn
/Fe ratio (up to 400) and low concentrations of transition metals. The
REE pattern is similar to other marine low-temperature hydrothermal a
nd sub-oxic diagenetic Mn deposits, low total REE abundance and strong
negative Ce anomaly. The deposit consists of major todorokite with mi
nor buserites, showing a hydrothermal signature. Bladelike crystals of
the minerals typically grow within open tubes (several mm thick) and
lack detrital minerals. All data indicate a low-temperature hydrotherm
al or cold seep origin, or less likely a sub-oxic diagenetic origin. T
his unusual manganese deposit from a pelagic environment is thought to
have formed on the sea floor from Mn-bearing waters that passed throu
gh sediments or basement rocks. We speculate that intraplate water cir
culation took place during the Late Pliocene to Pleistocene due to the
uplift and/or block faulting after the deposition of pelagic Pliocene
sediments. (C) 1997 Elsevier Science B.V.