INFLUENCE OF INTEGRATOR PARAMETERS ON ESTIMATES CALCULATED WITH THE STATISTICAL-MODEL OF OVERLAP

Citation
D. Bowlin et al., INFLUENCE OF INTEGRATOR PARAMETERS ON ESTIMATES CALCULATED WITH THE STATISTICAL-MODEL OF OVERLAP, Journal of chromatography, 677(2), 1994, pp. 307-318
Citations number
20
Categorie Soggetti
Chemistry Analytical
Journal title
Volume
677
Issue
2
Year of publication
1994
Pages
307 - 318
Database
ISI
SICI code
Abstract
The effect of the slope and area thresholds of a digital integrator on the calculation of component numbers with the statistical model of ov erlap (SMO) is critiqued. As these thresholds increase, the numbers of maxima recognized by the integrator and components calculated with th e SMO both decrease. With modest changes in threshold, the maxima and component numbers decrease proportionally, such that their ratio remai ns constant. For larger changes in threshold, the number of components usually decreases more rapidly than the number of maxima. Computer si mulations are developed that confirm the general trend of these observ ations. The implications of these variations are discussed.