The reduction of Cr(VI) by steel wool and the precipitation of reduced
chromium by CaCO3 powder and NaOH solution were investigated in conti
nuous and batch systems, respectively. The effects of acid and initial
Cr(VI) concentrations, volumetric sate and temperature of solution on
Cr(VI) reduction were studied. The results showed that the reduction
of Cr(VI), to a large extent, depended on, and increased with, acid co
ncentration. The Cr(III) and iron ions in the reduced solution were co
mpletely precipitated by using NaOH solution at appropriate alkaline c
onditions. If was concluded that CaCO3 powder could be used as a cheap
precipitant for Cr(III) ions. But the iron ions in the reduced soluti
on could not be fully removed by using this precipitant. (C) 1997 Else
vier Science Ltd.