Mg. Zhu et Ddl. Chung, IMPROVING THE STRENGTH OF BRAZED JOINTS TO ALUMINA BY ADDING CARBON-FIBERS, Journal of Materials Science, 32(20), 1997, pp. 5321-5333
The addition of short, bare, carbon fibres to a silver-based active br
azing alloy (63Ag-34Cu-2Ti-1Sn) resulted in up to 30% improvement in t
he shear/tensile joint strength of brazed joints between stainless ste
el and alumina. The optimum fibre volume fraction in the brazing mater
ial was 12%. This improvement is attributed to the thinning and micros
tructural simplification of the alumina/braze reaction product (titani
um-rich) layer, the softening of the brazing alloy matrix, the strengt
hening of the braze and the reduction of the coefficient of thermal ex
pansion. The depth of titanium diffusion into the alumina was decrease
d by the fibre addition. The first two effects are due to the absorpti
on of titanium by the fibres. This absorption resulted in less titaniu
m in the brazing alloy matrix, a braze/fibre particulate reaction prod
uct (titanium-rich) on the fibres and the diffusion of titanium into t
he fibres. In contrast, the use of an active brazing alloy with a lowe
r titanium content but without carbon fibres gave much weaker joints.