In fractional washing the countercurrent filtrate overflow is divided
into fractions with different physical properties (concentration, pH,
temperature), The fractions are used separately in earlier stages of w
ashing. The purpose of this paper was to test theoretically the possib
le benefits of fractional washing in post-O-2 washing. A diffusion was
hing model was used to predict the washing efficiency in relation to d
issolved organic material in various fractional process configurations
. The process configurations studied had one to three filtrate fractio
ns with various chemical concentrations in countercurrent two-stage po
st-O-2 washing. Fractional washing improved displacement efficiency si
gnificantly for some of the calculated examples, Fractional washing pr
oved to be especially beneficial for the removal of quick leaching com
ponents, (such as metal ions and small molecules). Slow leaching behav
ior reduced the potential benefits of fractional washing. Long retenti
on times are also essential in fractional washing in order to achieve
good results in washing out dissolved organic material.