A NEW O-NITROBENZYL PHOTOCLEAVABLE LINKER FOR SOLID-PHASE SYNTHESIS

Citation
R. Rodebaugh et al., A NEW O-NITROBENZYL PHOTOCLEAVABLE LINKER FOR SOLID-PHASE SYNTHESIS, Tetrahedron letters, 38(44), 1997, pp. 7653-7656
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
44
Year of publication
1997
Pages
7653 - 7656
Database
ISI
SICI code
0040-4039(1997)38:44<7653:ANOPLF>2.0.ZU;2-J
Abstract
A new photolabile linker, 7, was synthesized in high yield from commer cially available starting materials. Irradiation of polymer supports c ontaining 7 produced the desired amino acid and sugar products in high yields. The utility of 7 was demonstrated through the synthesis and p hotocleavage of a branched trimannan from a polymer support. (C) 1997 Elsevier Science Ltd.