A PD(O)-CATALYZED ROUTE TO FUNCTIONALIZED BETA-C-GLYCOSIDES FROM BETA-C-GLYCOSYLALDEHYDES

Authors
MICHELET V GENET JP DUJARDIN G
Citation
V. Michelet et al., A PD(O)-CATALYZED ROUTE TO FUNCTIONALIZED BETA-C-GLYCOSIDES FROM BETA-C-GLYCOSYLALDEHYDES, Tetrahedron letters, 38(44), 1997, pp. 7741-7744
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
44
Year of publication
1997
Pages
7741 - 7744
Database
ISI
SICI code
0040-4039(1997)38:44<7741:APRTFB>2.0.ZU;2-K
Abstract
C-glycosides are synthesized in five steps starting from beta-C-glycos ylaldehydes 1 and 2. The key step is a Pd(0)-catalyzed alkylation that leads regio and stereoselectively to exotic compounds by formation of C-C and C-N bonds. (C) 1997 Published by Elsevier Science Ltd.