GENERATION AND INTRAMOLECULAR CYCLIZATION OF DIFLUOROALKYL RADICALS VIA SINGLE-ELECTRON TRANSFER FROM THE BENZENESELENOLATE ANION - SYNTHESIS OR ALPHA,ALPHA-DINUORO-GAMMA-LACTAMS

Authors
UNEYAMA K YANAGIGUCHI T ASAI H
Citation
K. Uneyama et al., GENERATION AND INTRAMOLECULAR CYCLIZATION OF DIFLUOROALKYL RADICALS VIA SINGLE-ELECTRON TRANSFER FROM THE BENZENESELENOLATE ANION - SYNTHESIS OR ALPHA,ALPHA-DINUORO-GAMMA-LACTAMS, Tetrahedron letters, 38(44), 1997, pp. 7763-7764
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
44
Year of publication
1997
Pages
7763 - 7764
Database
ISI
SICI code
0040-4039(1997)38:44<7763:GAICOD>2.0.ZU;2-M
Abstract
Several alpha,alpha-difluoro-gamma-lactams (2) were prepared by radica l cyclization of amides (1) which were initiated by a single electron transfer (SET) process from the benzeneselenolate anion. Deselenation of these lactams (2) gave the corresponding alpha,alpha-difluoro-beta- exomethylene lactams (8). (C) 1997 Elsevier Science Ltd.