ASYMMETRIC DIELS-ALDER REACTION OF A CHIRAL AZLACTONE

Authors
BUNUEL E CATIVIELA C DIAZDEVILLEGAS MD
Citation
E. Bunuel et al., ASYMMETRIC DIELS-ALDER REACTION OF A CHIRAL AZLACTONE, Tetrahedron : asymmetry, 5(2), 1994, pp. 157-160
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
5
Issue
2
Year of publication
1994
Pages
157 - 160
Database
ISI
SICI code
0957-4166(1994)5:2<157:ADROAC>2.0.ZU;2-Y
Abstract
The chilal Z-azlactone derived from 1,2-O-isopropylidene-D-glyceraldeh yde underwent facial diastereoselective Diels-Alder reaction with cycl opentadiene. Catalyst and temperature dependence of the product ratio is described The absolute configuration of the major compound was esta blished by an X-ray crystallographic analysis.