ELECTROCHEMICAL OXIDATION AND REDUCTION OF RHODIUM AND IRIDIUM COMPLEXES WITH FULLERENES C-60 AND C-70

Authors
DENISOVICH LI PEREGUDOVA SM USATOV AV SIGAN AL NOVIKOV YN
Citation
Li. Denisovich et al., ELECTROCHEMICAL OXIDATION AND REDUCTION OF RHODIUM AND IRIDIUM COMPLEXES WITH FULLERENES C-60 AND C-70, Russian chemical bulletin, 46(7), 1997, pp. 1251-1257
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
7
Year of publication
1997
Pages
1251 - 1257
Database
ISI
SICI code
1066-5285(1997)46:7<1251:EOAROR>2.0.ZU;2-H
Abstract
The electrochemical behavior of rhodium and iridium complexes with ful lerenes C-60 and C-70 was Studied by cyclic voltammetry in a THF-tolue ne mixture. The complexes were found to be capable of oxidation and re duction. It was demonstrated that the in situ generation of metalloful lerene complexes in the electrochemical cell by the interaction of C-6 0 and C-70 With hydridocarbonylphosphine complexes of rhodium and irid ium, KM(CO)(PPh3)(3), is possible. The influence of structural factors and the action of CO2 on changes in the redox properties of fullerene complexes was considered.