SPECIFIC FEATURES OF THE INTERACTION OF METHYL ETHERS OF METHYL (METHYL-ALPHA-D-GALACTOPYRANOSIDE)URONATE WITH TRIMETHYLSILYL IONS IN THE GAS-PHASE

Authors
KADENTSEV VI KOLOTYRKINA NG STOMAKHIN AA CHIZHOV OS
Citation
Vi. Kadentsev et al., SPECIFIC FEATURES OF THE INTERACTION OF METHYL ETHERS OF METHYL (METHYL-ALPHA-D-GALACTOPYRANOSIDE)URONATE WITH TRIMETHYLSILYL IONS IN THE GAS-PHASE, Russian chemical bulletin, 46(7), 1997, pp. 1261-1263
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
7
Year of publication
1997
Pages
1261 - 1263
Database
ISI
SICI code
1066-5285(1997)46:7<1261:SFOTIO>2.0.ZU;2-M
Abstract
Specific features of the interaction between trimethylsilyl ions and m ethyl (methyl-alpha-D-galactopyranoside)uronate and its methyl ethers were revealed. It was shown that a hydrogen atom is generated when the trimethylsilyl ion is located at hydroxyl group. This atom migrates o ver the methoxy and hydroxyl groups toward the glycoside methoxy group , resulting in the formation of [Me+SiMe3-MeOH](+) ions.