CONFIGURATIONALLY STABLE ASYMMETRIC NITROGEN ATOM IN THE PALLADIUM(II) AMINOPHOSPHINE COMPLEX

Authors
DUNINA VV GOLOVAN EB GULYUKINA NS GRISHIN YK BELETSKAYA IP
Citation
Vv. Dunina et al., CONFIGURATIONALLY STABLE ASYMMETRIC NITROGEN ATOM IN THE PALLADIUM(II) AMINOPHOSPHINE COMPLEX, Russian chemical bulletin, 46(7), 1997, pp. 1331-1334
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
7
Year of publication
1997
Pages
1331 - 1334
Database
ISI
SICI code
1066-5285(1997)46:7<1331:CSANAI>2.0.ZU;2-S
Abstract
The synthesis of a new optically active aminophosphine ligand i-Pramph os, containing a potentially stereogenic nitrogen atom, from (S)-N-iso propyl-N-methyl-alpha-methylbenzylamine is described; its complex with palladium(II) chloride was obtained. NMR spectroscopy revealed that t he coordination of the aminophosphine with the metal resulted in stere ospecific locking of the donor nitrogen atom in only one of two possib le configurations.