LEAD-PROMOTED BARBIER-TYPE REACTION OF ALDEHYDES WITH PROPARGYL BROMIDES IN AQUEOUS-MEDIA

Authors
ZHOU JY SUN GF ZHANG MF JIA Y WU SH
Citation
Jy. Zhou et al., LEAD-PROMOTED BARBIER-TYPE REACTION OF ALDEHYDES WITH PROPARGYL BROMIDES IN AQUEOUS-MEDIA, Chinese journal of chemistry, 15(4), 1997, pp. 361-365
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chinese journal of chemistry → ACNP
ISSN journal
1001604X
Volume
15
Issue
4
Year of publication
1997
Pages
361 - 365
Database
ISI
SICI code
1001-604X(1997)15:4<361:LBROAW>2.0.ZU;2-H
Abstract
This paper reports that the reaction of the propargyl bromides with al dehydes promoted by powdered lead in aqueous media. The selectivity an d possible mechanism of these reactions are discussed. The yields of p roducts for reaction of propargyl bromide are 31 similar to 71%. The r atios of allenyl alcohol and homopropargyl alcohol are 1:1.5 to 1:3. T he product for reaction of phenyl propargyl bromide is allenyl alcohol and the yields are 52 similar to 84%.