ELECTRON-SCATTERING FROM SO2 MOLECULES - ELASTIC PROCESSES AND ROTATIONAL EXCITATIONS

Citation
Fa. Gianturco et al., ELECTRON-SCATTERING FROM SO2 MOLECULES - ELASTIC PROCESSES AND ROTATIONAL EXCITATIONS, Journal of physics. B, Atomic molecular and optical physics, 30(20), 1997, pp. 4535-4557
Citations number
31
Categorie Soggetti
Physics, Atomic, Molecular & Chemical",Optics
ISSN journal
09534075
Volume
30
Issue
20
Year of publication
1997
Pages
4535 - 4557
Database
ISI
SICI code
0953-4075(1997)30:20<4535:EFSM-E>2.0.ZU;2-N
Abstract
Quantum calculations are carried out for the scattering of electrons f rom sulphur dioxide molecules in the energy range from about 1.0 eV up to 30 eV. Integral and differential cross sections are obtained for t he elastic process and for the excitation processes of the target asym metric rotor into various final rotational levels. Comparison with exp erimental data, both of the momentum transfer cross sections and the a ngular distributions, indicates rather good agreement between measured and computed values over the whole range of the examined energies, wh ile the integral elastic cross sections (rotationally summed) show dis agreement at low energy with the experimental estimates. Born correcti ons to the calculations are also shown to provide the correct behaviou r of the forward scattering angular distributions and a reliable guide to experimental extrapolation procedures.