INITIAL-STAGE OF STRUCTURE FORMATION DURI NG PHASE-SEPARATION AND CURE OF POLYMER BLENDS

Citation
Sa. Shaginyan et Li. Manevich, INITIAL-STAGE OF STRUCTURE FORMATION DURI NG PHASE-SEPARATION AND CURE OF POLYMER BLENDS, Vysokomolekularnye soedinenia. Seria A, 39(8), 1997, pp. 1338-1342
Citations number
12
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
39
Issue
8
Year of publication
1997
Pages
1338 - 1342
Database
ISI
SICI code
0507-5475(1997)39:8<1338:IOSFDN>2.0.ZU;2-E
Abstract
A model is proposed that describes a combined process of cure and phas e separation in a multicomponent polymer blend. A size distribution fu nction of the concentration inhomogeneities in the initial process sta ge is derived. Conditions necessary for the detection of these inhomog eneities in the light scattering experiments are considered The concen tration and temperature dependences of the functional soup conversion and the number-average molecular mass are determined for the microstru ctures formed in the linear process stage away from the spinodal of th e initial blend.