HIGHLY ISOTACTIC OPTICALLY-ACTIVE METHACRYLATE POLYMERS BY FREE-RADICAL CYCLOPOLYMERIZATION

Authors
ZHENG SY SOGAH DY
Citation
Sy. Zheng et Dy. Sogah, HIGHLY ISOTACTIC OPTICALLY-ACTIVE METHACRYLATE POLYMERS BY FREE-RADICAL CYCLOPOLYMERIZATION, Tetrahedron, 53(45), 1997, pp. 15469-15485
Citations number
76
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
45
Year of publication
1997
Pages
15469 - 15485
Database
ISI
SICI code
0040-4020(1997)53:45<15469:HIOMPB>2.0.ZU;2-0
Abstract
Isospecific free radical cyclopolymerization of tartrate-based monomer s gives polymers with very high optical rotations. Circular dichroism and polarimetric measurements suggest the polymers are rigid and order ed. Their high resistance to solvolysis suggests potential application s in chiral chromatography. (C) 1997 Elsevier Science Ltd.