Measurements of positive ion composition in the payload bay of the Spa
ce Shuttle confirm that the vernier reaction control system rocket eng
ines cause major changes in the shuttle plasma environment. Previously
reported measurements of increases and decreases in ambient and conta
minant ion fluxes are corroborated and are shown to depend on the atti
tude of the shuttle, the direction of exhaust plume flow, and the poin
ting direction of the mass spectrometer sampling orifice. The column d
ensity of exhaust neutrals and the length of the effective column are
both roughly estimated from the magnitude and time response of the red
uction in ambient O+ flux. The measurements are consistent with contro
l of the contaminant ion motions by the Earth's magnetic field. Contam
inant ions are detected only if the mass spectrometer is approximately
aligned with the plane of ion motion perpendicular to the magnetic fi
eld vector, and only if the plume gases expand into a region of space
from which the pickup trajectories are directed back into the instrume
nt sampling orifice. The degree to which contaminant ions are picked u
p by the magnetic field depends on the chemical dynamics of the ion-mo
lecule reaction that formed them. The appearance of large fluxes of io
ns at mass 28 cannot be explained by the chemistry of O+ reacting with
the principal exhaust neutral species. Electron impact ionization of
neutral N2 to give N2+ is proposed as a possible source for this mass
28 ion.