A. Hernando et al., HIGH-TEMPERATURE LARGE DIAMAGNETISM IN BALL-MILLED SR0.6CA0.4CUO2, Physical review. B, Condensed matter, 56(13), 1997, pp. 7800-7803
The observation of a large effective diamagnetic susceptibility of -3.
4 X 10(-6) emu g(-1) Oe(-1) up to temperatures above 1000 K in highly
deformed ball-milled Sr0.6Ca0.4CuO2 is reported. These samples do not
exhibit superconductivity at low temperature. This anomalously strong
diamagnetism increases with milling time and reaches a maximum value a
fter 500 h of milling. A model is proposed in which excess holes, intr
oduced during milling, have wave functions that are extended over the
CuO2 planes of the crystallites, resulting in large values of the diam
agnetic susceptibility.