We have performed synchrotron x-ray scattering experiments on single c
rystals of ErNi2B2C. Below 6.3 K, the (2,0,0) Bragg peak splits, indic
ating a tetragonal-to-orthorhombic distortion. The mismatch between th
e a and b lattice parameters appears coincident with the onset of long
-range antiferromagnetic order and increases continuously with decreas
ing temperature, reaching a value of a/b-1 approximate to 0.2% at 3.7
K.