M. Chua et Pa. Tanner, ANALYSIS OF (F-7(0))GAMMA(1G)-]GAMMA(1G)(D-5(0)) 2-PHOTON TRANSITION OF SM2+ IN SRF2, Physical review. B, Condensed matter, 56(13), 1997, pp. 7967-7973
The two-photon transition intensity of the (F-7(0))Gamma(1g)-->Gamma(1
g)(D-5(0)) transition of the 4f(6)-ion Sm2+ in SrF2 has been investiga
ted both in Judd-Pooler and direct formalisms. Although the agreement
between the different calculations may be regarded as satisfactory, th
e direct calculation provides additional information concerning the tr
ansition intensity mechanism. The dominant pathway is found to involve
the 4f(5)5d(1) intermediate core state H-6. The effects of changing t
he intermediate state baricenter have been investigated for both calcu
lations, and the Judd-Pooler calculation becomes closer in agreement w
ith the direct calculation as the energy baricenter increases.