The YbCu5 phase with C15b structure has been prepared by a high-pressu
re technique, and its physical properties have been investigated. The
temperature dependence of magnetic susceptibility, electrical resistiv
ity, and specific heat show Kondo-lattice formation. Furthermore, a he
avy Fermi-liquid state without magnetic ordering down to 2.0 K is foun
d to evolve below about 6 K. The electronic specific heat coefficient
gamma is enhanced to values as large as to 550 mJ/mol K-2. The magneti
zation measured up to 40 T at 1.6 K has a field dependence which is ex
pected for a Kondo system when the total angular momentum is J>1. All
results are in good agreement with the extrapolation of the previous r
esults of YbCu5-xAgx (0.125 less than or equal to x less than or equal
to 1.0) for x-->0. The concentration dependence of characteristic tem
peratures of YbCu5-xAgx can be quantitatively explained by the chemica
l pressure effect within the compressible Kondo model for the full ran
ge of Ag concentration (0.0 less than or equal to x less than or equal
to 1.0). The origins of Kondo-lattice formation in YbCu4Ag and the va
lence transition in YbCu4In are discussed.