THE INFLUENCE OF ROTATIONAL RELAXATION ON THE UNRESOLVED Q-BRANCH DENSITY-SHIFT INDUCED BY VIBRATIONAL DEPHASING

Authors
STREKALOV ML
Citation
Ml. Strekalov, THE INFLUENCE OF ROTATIONAL RELAXATION ON THE UNRESOLVED Q-BRANCH DENSITY-SHIFT INDUCED BY VIBRATIONAL DEPHASING, Chemical physics, 222(2-3), 1997, pp. 223-228
Citations number
29
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics → ACNP
ISSN journal
03010104
Volume
222
Issue
2-3
Year of publication
1997
Pages
223 - 228
Database
ISI
SICI code
0301-0104(1997)222:2-3<223:TIORRO>2.0.ZU;2-P
Abstract
The density dependence of the contributions of elastic vibrational dep hasing and rotationally inelastic collisions into the overall shift of the Raman e-branch profile of nitrogen has been theoretically studied . The results have been found to accurately reproduce the frequency sh ift measurements over a wide density range (10-900 amagat), also inclu ding the liquid phase. (C) 1997 Elsevier Science B.V.