SYNTHESIS OF MACROCYCLIC BIS(DITHIOCARBONIC ESTER)S AND BIS(THIOCARBAMATE)S FROM DIETHYLENE, TRIETHYLENE, AND TETRAETHYLENE GLYCOLS

Authors
FUKADA N TANAKA T FUKUYA T TAKEDA Y
Citation
N. Fukada et al., SYNTHESIS OF MACROCYCLIC BIS(DITHIOCARBONIC ESTER)S AND BIS(THIOCARBAMATE)S FROM DIETHYLENE, TRIETHYLENE, AND TETRAETHYLENE GLYCOLS, Bulletin of the Chemical Society of Japan, 70(10), 1997, pp. 2515-2518
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
70
Issue
10
Year of publication
1997
Pages
2515 - 2518
Database
ISI
SICI code
0009-2673(1997)70:10<2515:SOMBEA>2.0.ZU;2-Z
Abstract
The reaction of dipotassium bis(dithiocarbonate)s from diethylene, tri ethylene, and tetraethylene glycols with dibromoalkanes or ethereal ox ygen-containing diiodides under high-dilution conditions gave 1:1 reac tion products, 14-25-membered macrocyclic bis(dithiocarbonic ester)s. From dimethyl esters of the bis(dithiocarbonic acid)s and diamino-alka nes or ethereal oxygen-containing diamines, macrocyclic bis(thiocarbam ate)s were obtained.