T. Eisner et al., DEFENSIVE PRODUCTION OF QUINOLINE BY A PHASMID INSECT (OREOPHOETES PERUANA), Journal of Experimental Biology, 200(19), 1997, pp. 2493-2500
Adults and nymphs of the Peruvian stick insect Oreophoetes peruana (or
der Phasmatodea) have a pair of thoracic glands from which they discha
rge a malodorous fluid when disturbed, The secretion contains a single
volatile component, quinoline, Quinoline has not been reported previo
usly from an animal source, The compound proved repellent or topically
irritant in assays with ants, spiders, cockroaches and frogs, O., per
uana nymphs, at molting, do not extricate the shed cuticular lining of
the glands, thereby managing not to lose their secretory supply when
they cast their skin, They are able, as a consequence, to discharge se
cretion even while still teneral after molting.