STRUCTURAL REINVESTIGATION OF BA3ZR2S7 BY SINGLE-CRYSTAL X-RAY-DIFFRACTION

Authors
CHEN BH EICHHORN B WONGNG WN
Citation
Bh. Chen et al., STRUCTURAL REINVESTIGATION OF BA3ZR2S7 BY SINGLE-CRYSTAL X-RAY-DIFFRACTION, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 161-164
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
2
Pages
161 - 164
Database
ISI
SICI code
0108-2701(1994)50:<161:SROBBS>2.0.ZU;2-Y
Abstract
Single crystals of barium zirconium sulfide, Ba3Zr2S7, were prepared f rom BaS, Zr and S at 1323 K by using a BaCl2 flux. The compound belong s to the Ruddlesden-Popper (A(n+1) B(n)X3n+1) family with A = Ba, B = Zr, X = S and n = 2. It is isostructural to Sr3Ti2O7 and crystallizes in alternately stacked double perovskite BaZrS3 layers and rocksalt Ba S layers.