BRIDGED BIS(DICARBADODECABORANE)COBALT(III)

Authors
CISAROVA I MALY K HUMMEL L
Citation
I. Cisarova et al., BRIDGED BIS(DICARBADODECABORANE)COBALT(III), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 198-200
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
2
Pages
198 - 200
Database
ISI
SICI code
0108-2701(1994)50:<198:BB>2.0.ZU;2-D
Abstract
The molecule of bis[1,2-dicarba-3-cobalta-closo-dodecaborane(II)], [Co (C7H26B18NO2)], comprises two dicarbaborane ligands coordinated to the Co atom to form a 'sandwich' compound linked by pentagonal faces. The ligands are also linked by a monoatomic nitrogen bridge to which a me thoxycarbonylmethyl group is bound, B-N bond lengths being 1.577 (4) a nd 1.563 (4) angstrom.