S,9SR,12RS)-2,5,9,12-TETRAAZATRIDECANE]COBALT(III) PERCHLORATE, [COCL2(C9H24N4)]CLO4

Authors
LU TH LAI CY CHUNG CS
Citation
Th. Lu et al., S,9SR,12RS)-2,5,9,12-TETRAAZATRIDECANE]COBALT(III) PERCHLORATE, [COCL2(C9H24N4)]CLO4, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 202-203
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
2
Pages
202 - 203
Database
ISI
SICI code
0108-2701(1994)50:<202:SP[>2.0.ZU;2-K
Abstract
The coordination geometry about Co(III) is slightly distorted octahedr al. The four donor N atoms of the tetraamine form the equatorial plane of the coordination octahedron and two Cl ligands occupy the apices. The alternate five-, six- and five-membered chelate rings have stable skew, chair and skew conformations, respectively. The perchlorate grou p binds the tetraamine groups through weak hydrogen bonds.