Ka. Khan et al., ENERGY-RESOLVED AND ANGLE-RESOLVED FRAGMENTATION OF ETHYL-BROMIDE ON GAAS(110), JOURNAL OF PHYSICAL CHEMISTRY B, 101(44), 1997, pp. 9077-9086
Angle- and mass-resolved time-of-flight (TOF) measurements are used to
probe the photodynamics and molecular orientation of C2H5Br on GaAs(1
10). Temperature-programmed desorption measurements indicate that this
species is molecularly adsorbed with a binding energy of 0.43 eV. Aft
er photoinduced C-Br bond cleavage two channels for ethyl fragments ej
ected are observed in the TOF: one resulting from direct ejection alon
g the C-Br bond with a kinetic energy that varies from 0.6 to 1.1 eV,
depending upon incident excitation wavelength, and the other, resultin
g from transient scattering from the surface potential energy well wit
h a kinetic energy of 0.4 eV. Additionally, the kinetic energy of the
directly ejected fragments varies with detection angle, a behavior con
sistent with a fragment-surface potential with normal energy scaling.
The TOF measurements also indicate that, at coverages of <1 ML, the C2
H5Br is oriented with the C-Br bond at an angle near 30 degrees from t
he surface normal in the [0 (1) over bar] direction. This result is in
accord with earlier NEXAFS and TOF measurements and ab initio calcula
tions of CH3Br on the same surface, which show that such a polar molec
ule is individually oriented by electrostatic interaction with the sur
face GaAs dipoles.