1,1'-BIS(DIPHENYLPHOSPHINE-OXIDE)FERROCENE DIHYDRATE

Authors
MUNYEJABO V POSTEL M ROUSTAN JL BENSIMON C
Citation
V. Munyejabo et al., 1,1'-BIS(DIPHENYLPHOSPHINE-OXIDE)FERROCENE DIHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 224-226
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
2
Pages
224 - 226
Database
ISI
SICI code
0108-2701(1994)50:<224:1D>2.0.ZU;2-4
Abstract
The title compound, 1,1'-ferrocenediylbis(diphenylphosphine oxide) dih ydrate, [Fe(C17H14OP)2].2H2O, was obtained by oxidation of bis(dipheny lphosphino)ferrocene with trimethylamine oxide. The Fe atom sits on a molecular centre of symmetry and the two Cp rings are planar with a st aggered configuration. The two phosphoryl groups are trans with respec t to the Fe(Cp)2 group.