IS[BIS(DIMETHYL-SULFOXIDE)-TRIFLUOROZIRCONIUM(IV)]

Authors
ALCOCK NW ERRINGTON W GOLBY SL PATTERSON SMC WALLBRIDGE MGH
Citation
Nw. Alcock et al., IS[BIS(DIMETHYL-SULFOXIDE)-TRIFLUOROZIRCONIUM(IV)], Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 226-227
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
2
Pages
226 - 227
Database
ISI
SICI code
0108-2701(1994)50:<226:I>2.0.ZU;2-O
Abstract
The title compound, [ZrF4(C2H6OS)2]2, is a centrosymmetric fluorine-br idged dimer. The seven-coordinate Zr atoms are in a pentagonal bipyram idal environment with F atoms above and below the pentagonal plane. Th e average Zr-F bridging distance of 2.167 (4) angstrom is significantl y longer than the terminal distances which range from 1.973 (4) to 2.0 01 (4) angstrom.