SYNTHESIS AND CHARACTERIZATION OF A NEW ZINC PHOSPHATE, [NH3(CH2)(4)NH3](2-), CONTAINING ALTERNATING INORGANIC-ORGANIC LAYERS()[ZN2P3O9(OH)(3)](2)

Authors
NATARAJAN S ATTFIELD MP CHEETHAM AK
Citation
S. Natarajan et al., SYNTHESIS AND CHARACTERIZATION OF A NEW ZINC PHOSPHATE, [NH3(CH2)(4)NH3](2-), CONTAINING ALTERNATING INORGANIC-ORGANIC LAYERS()[ZN2P3O9(OH)(3)](2), Journal of solid state chemistry, 132(2), 1997, pp. 229-234
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
132
Issue
2
Year of publication
1997
Pages
229 - 234
Database
ISI
SICI code
0022-4596(1997)132:2<229:SACOAN>2.0.ZU;2-B
Abstract
A new zinc phosphate [NH3(CH2)(4)NH3](2+) [Zn2P3O9(OH)(3)](2-) was syn thesized under acidic conditions at room temperature. It crystallizes in triclinic space group P (1) over bar (No. 2) with lattice parameter s a = 8.4003(8), b = 8.6690(7), c = 10.3523(15) Angstrom, alpha = 88.2 37(1), beta = 77.732(1), gamma = 86.406(1)degrees V = 735.1, Z = 2, R = 0.33, and R-w = 0.041. The structure consists of alternating inorgan ic and organic layers, The inorganic layers are held together by stron g hydrogen bonding, creating cavities in which diprotonated diaminobut ane molecules reside. (C) 1997 Academic Press.