THERMAL-DECOMPOSITION OF COPPER(II) DICALCIUM(II) FORMATE

Authors
DEPERAZZO PK LEYVA AG POLLA G PARISI F DEBENYACAR MAR SMICHOWSKI P LANZA H
Citation
Pk. Deperazzo et al., THERMAL-DECOMPOSITION OF COPPER(II) DICALCIUM(II) FORMATE, Journal of solid state chemistry, 132(2), 1997, pp. 235-238
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry → ACNP
ISSN journal
00224596
Volume
132
Issue
2
Year of publication
1997
Pages
235 - 238
Database
ISI
SICI code
0022-4596(1997)132:2<235:TOCDF>2.0.ZU;2-T
Abstract
The unit cell obtained through X-ray single crystal analysis of the sy nthetized CuCa2(HCOO)(6) crystals corresponds to a supercell of the ba sic structure described by M. Sanchis et al, (Inorg. Chem. 31, 2915 (1 992)), Thermal decomposition of this sample shows two stages up to 300 degrees C; the first can be related to the superstructure, and the se cond corresponds to the breaking down of the remaining copper formate structural units and the simultaneous decomposition of the sample. (C) 1997 Academic Press.