K. Fukui et al., SURFACE AND BULK-PASSIVATED LARGE-AREA MULTICRYSTALLINE SILICON SOLAR-CELLS, Solar energy materials and solar cells, 48(1-4), 1997, pp. 219-228
We have investigated the surface and bulk passivation technique on lar
ge-area multicrystalline silicon solar cells, a large open-circuit vol
tage has been obtained for cells oxidized to passivate the surface and
hydrogen annealed after deposition of silicon nitride film on both su
rfaces by plasma CVD method (P-SiN) to passivate the bulk. The texture
surface like pyramid structure on multicrystalline silicon surface ha
s been obtained uniformly using reactive ion etching (RIE) method. Com
bining these RIE method and passivation schemes, the conversion effici
ency of 17.1% is obtained on 15 cm x 15 cm multicrystalline silicon so
lar cell. Phosphorus diffusion, BSF formation, passivation technique a
nd contact metallization for low-cost process sequences are also descr
ibed in this paper.