TIN-PUMMERER REARRANGEMENT IN THE SYNTHESIS OF O,S-ACETAL DERIVATIVES

Citation
J. Hatlelid et al., TIN-PUMMERER REARRANGEMENT IN THE SYNTHESIS OF O,S-ACETAL DERIVATIVES, Acta chemica Scandinavica, 51(11), 1997, pp. 1092-1095
Citations number
14
Categorie Soggetti
Chemistry,Biology
Journal title
ISSN journal
0904213X
Volume
51
Issue
11
Year of publication
1997
Pages
1092 - 1095
Database
ISI
SICI code
0904-213X(1997)51:11<1092:TRITSO>2.0.ZU;2-V
Abstract
alpha-Thioalkyl esters and carbonates have been prepared by a tin-Pumm erer rearrangement in reactions of alpha-stannylated sulfoxides with a cid chlorides or chloroformates, respectively. Acid chlorides have a h igher reactivity than chloroformates in this reaction.