K. Mukherjee et al., SURFACE-ENHANCED RAMAN-SPECTROSCOPIC STUDY OF ISOMERIC FORMYLTHIOPHENES IN SILVER COLLOID, Journal of colloid and interface science, 193(2), 1997, pp. 286-290
Surface enhanced Raman (SER) spectra of 2- and 3-formyltiophenes (2FT
and 3FT) in silver colloids are compared with their normal Raman spect
ra in bulk and in acetonitrile solution. Experimental results indicate
adsorption of 2FT on metal surface through the sulfur and the oxygen
atoms with the ring plane vertical to the metal surface, whereas the r
ing plane of the 3FT molecule is inclined to the surface, Moreover, th
e SER spectrum of 2FT molecule predicts the existence of syn-form of t
his molecule in the adsorbed state because of large enhancement of the
carbonyl stretching mode. Concentration dependence of relative enhanc
ement infers the monolayer formation on metal surface at a specific co
ncentration, implying strong evidence of chemisorption of the adsorbat
es, The excitation profile of C=C symmetric stretching mode of 2FT sug
gests classical plasmon resonance as the main contributor to surface e
nhancement. (C) 1997 Academic Press.