TRAVELING WAVES IN AN OPEN QUADRATIC AUTOCATALYTIC CHEMICAL-SYSTEM

Citation
Ab. Finlayson et Jh. Merkin, TRAVELING WAVES IN AN OPEN QUADRATIC AUTOCATALYTIC CHEMICAL-SYSTEM, Journal of mathematical chemistry, 21(3), 1997, pp. 305-321
Citations number
16
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
21
Issue
3
Year of publication
1997
Pages
305 - 321
Database
ISI
SICI code
0259-9791(1997)21:3<305:TWIAOQ>2.0.ZU;2-L
Abstract
The travelling waves that are initiated in an autocatalytic reaction-d iffusion system with quadratic rate law are considered. The system is modelled on the basis of a continuous-flow, unstirred reactor. The mod el is used to determine whether any of the complex structures reported for cubic autocatalytic reaction-diffusion systems can also be observ ed in the quadratic model. This is found not to be the case. The range of behaviour of the quadratic model is much less complex, with only f ront waves being initiated under the necessary conditions, which are e stablished. There are, however, some unusual transient features to be found after the initial passage of the wave front.