Gv. Yukhnevich et Eg. Tarakanova, CONCERNING THE PROBLEM OF TEMPERATURE-CHANGES IN THE INTENSITY OF CONTINUOUS ABSORPTION IN THE SPECTRA OF COMPLEXES WITH SYMMETRICAL H-BOND, Russian chemical bulletin, 46(8), 1997, pp. 1383-1385
The effect of temperature on the spectra of anharmonic vibrations of c
omplexes with symmetric H-bonds was simulated and considered using H3O
2- and H5O2+ ions as an example. The intensity of continuous absorptio
n observed in the IR spectra of such types of complexes is virtually i
ndependent of temperature.