ESR STUDY OF FREE-RADICAL INTRAMOLECULAR TRANSFER OF A HYDROGEN-ATOM - MECHANISMS AND KINETICS OF THE REACTIONS

Authors
RADZIG VA KOSTRITSA SN
Citation
Va. Radzig et Sn. Kostritsa, ESR STUDY OF FREE-RADICAL INTRAMOLECULAR TRANSFER OF A HYDROGEN-ATOM - MECHANISMS AND KINETICS OF THE REACTIONS, Russian chemical bulletin, 46(8), 1997, pp. 1403-1406
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
8
Year of publication
1997
Pages
1403 - 1406
Database
ISI
SICI code
1066-5285(1997)46:8<1403:ESOFIT>2.0.ZU;2-Z
Abstract
A method for preparing >Si(R-1)(R-2(.)) structures (R-1 = CH3, CD3, or CH2-CH3, R-2(.) = CH2-CH2. or CD2-CD2 .) grafted to a silica surface is developed. The reactions of intramolecular transfer of H (D) atoms between the R-1 and R-2(.) fragments were studied by ESR. The directio ns and kinetic parameters of these reactions were established.