CONFORMATIONAL-ANALYSIS OF THE [(C5H4CR'R'')(2)M](2+) DICATIONS (M = RU, OS) AS A TOOL FOR DETERMINING THEIR ONIUM OR DICARBOCATION STRUCTURE

Authors
KREINDLIN AZ RYBINSKAYA MI PETROVSKII PV
Citation
Az. Kreindlin et al., CONFORMATIONAL-ANALYSIS OF THE [(C5H4CR'R'')(2)M](2+) DICATIONS (M = RU, OS) AS A TOOL FOR DETERMINING THEIR ONIUM OR DICARBOCATION STRUCTURE, Russian chemical bulletin, 46(8), 1997, pp. 1458-1464
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
8
Year of publication
1997
Pages
1458 - 1464
Database
ISI
SICI code
1066-5285(1997)46:8<1458:COT[D(>2.0.ZU;2-G
Abstract
The [(Me2CC5H4)(2)M](2+) and [(Me(H)CC5H4)(2)M](2+) dications (M = Ru, Os) were generated and their precursors, dicarbinols, were synthesize d. H-1 NMR spectral analysis showed that the former dications have a d icarbocation structure. For the [(Me(H)CC5H4)(2)M](2+) dications, the energies of both the onium and dicarbocation structures are close, and compounds of both types can be simultaneously observed in solution.