J. Kuther et W. Tremel, STABILIZATION OF ARAGONITE ON THIOL-MODIFIED GOLD SURFACES - EFFECT OF TEMPERATURE, Chemical communications, (21), 1997, pp. 2029-2030
While the slow crystallization of calcium carbonate at 22 degrees C on
self-assembled omega-substituted alkylthiol surfaces yields in most c
ases, depending on the surface, the vaterite and calcite modifications
, elevating the temperature to 45 degrees C allows the stabilization o
f the aragonite modification as well.