CONDENSATION PRODUCTS FROM THE REACTIONS OF GLYOXAL WITH 2-SUBSTITUTED BENZYLAMINES - THE FORMATION AND CRYSTAL-STRUCTURES OF 2,2'-BI(1,2,3,4-TETRAHYDROQUINAZOLINE), AND 2-METHYLBENZYL)-2,4,6,8,10,12-HEXAAZAISOWURTZITANE

Authors
BATSANOV A COLE JC CRAMPTON MR HAMID J HOWARD JAK MILLAR R
Citation
A. Batsanov et al., CONDENSATION PRODUCTS FROM THE REACTIONS OF GLYOXAL WITH 2-SUBSTITUTED BENZYLAMINES - THE FORMATION AND CRYSTAL-STRUCTURES OF 2,2'-BI(1,2,3,4-TETRAHYDROQUINAZOLINE), AND 2-METHYLBENZYL)-2,4,6,8,10,12-HEXAAZAISOWURTZITANE, Perkin transactions. 2, (3), 1994, pp. 421-424
Citations number
8
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
3
Year of publication
1994
Pages
421 - 424
Database
ISI
SICI code
0300-9580(1994):3<421:CPFTRO>2.0.ZU;2-J
Abstract
Condensation of glyoxal with 2-aminobenzylamine produces the novel com pound 2,2'-bi(1,2,3,4-tetrahydroquinazoline), 6, the structure of whic h has been confirmed by X-ray crystallography. However, reaction of gl yoxal with other 2-substituted benzylamines yields hexabenzylhexaazais owurtzitanes. The crystal structure of the derivative prepared from 2- methylbenzylamine has been determined and is compared with that of the derivative from 4-chlorobenzylamine