S. Biernacki et al., TEMPERATURE-DEPENDENCE OF OPTICAL-TRANSITIONS BETWEEN ELECTRONIC-ENERGY LEVELS IN SEMICONDUCTORS, Physical review. B, Condensed matter, 49(7), 1994, pp. 4501-4510
We propose a model to describe temperature-dependent electronic transi
tions using an effective electron-ion interaction. We present a nonper
turbative calculation of the temperature dependence of the forbidden e
nergy gap of CdTe crystals. The results are compared with similar calc
ulations using the statistical-function method and both give good agre
ement with experimental data. It is also demonstrated that the thermal
expansion of the lattice plays a minor role for the temperature varia
tion of the electronic energy levels.