M. Jafar et D. Haneman, METAL INCORPORATION AND HEAT-PULSE MEASUREMENT IN AMORPHOUS-HYDROGENATED-SILICON QUANTUM DEVICES, Physical review. B, Condensed matter, 49(7), 1994, pp. 4605-4610
Amorphous-hydrogenated-silicon double Schottky switching diodes in whi
ch one contact is vanadium, formed to produce switching, can show disc
rete steps in the I-V characteristics in the ON state at resistances o
f h/2ne2 where n is an integer. We present experimental data to show t
hat the forming temperature of the device is in excess of 1100 K, whic
h can allow diffusion. Auger-electron-spectroscopy depth profiling sho
ws that the top electrode penetrates significantly into the film in th
e formed devices, as theorized previously to explain the quantum pheno
mena. An elemental compositional analysis of the diffused metal region
is presented. Resistance plots at various temperatures are consistent
with the matrix containing vanadium particles.