PHOSPHONIC SYSTEMS .13. ALKYLATION OF DIETHYL CYCLOHEXENYLPHOSPHONATES

Authors
GERBER JP MODRO TA
Citation
Jp. Gerber et Ta. Modro, PHOSPHONIC SYSTEMS .13. ALKYLATION OF DIETHYL CYCLOHEXENYLPHOSPHONATES, Phosphorus, sulfur and silicon and the related elements, 84(1-4), 1993, pp. 107-113
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
84
Issue
1-4
Year of publication
1993
Pages
107 - 113
Database
ISI
SICI code
1042-6507(1993)84:1-4<107:PS.AOD>2.0.ZU;2-B
Abstract
Alkylation of cyclohexenylphosphonates was found to proceed under very mild conditions. The reaction usually occurred in a regioselective fa shion with alpha-addition predominating. Steric effects were significa nt and had a bearing on the regioselectivity of the reaction.