REACTION OF ARYLMETHYLKETONES WITH SULFUR , SECONDARY-AMINES AND SULFUR-DIOXIDE

Authors
MATSCHINER H MASCHMEIER CP MAIER N HANSEN J
Citation
H. Matschiner et al., REACTION OF ARYLMETHYLKETONES WITH SULFUR , SECONDARY-AMINES AND SULFUR-DIOXIDE, Phosphorus, sulfur and silicon and the related elements, 84(1-4), 1993, pp. 223-230
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
84
Issue
1-4
Year of publication
1993
Pages
223 - 230
Database
ISI
SICI code
1042-6507(1993)84:1-4<223:ROAWS,>2.0.ZU;2-D
Abstract
The acetophenones 2 react with different sulfurdioxide-secondary amine adducts 1 and sulfur to yield the red-coloured zwitterionic 2-iminio- dithioacetates 3. Enamines can be proved to be intermediates in this r eaction. Thus enamines 5 and other derivatives such as acetophenone an il, acetophenone diethyl acetal and diphenacyl sulfide also give 3, In the absence of 1, 3a react with hydrogen sulfide to form the thioamid e of phenylacetic acid 8.