K. Ganesh et al., STABILIZATION OF THERMAL-DEGRADATION OF POLY(METHYL METHACRYLATE) BY POLYSULFIDE POLYMERS, Journal of applied polymer science, 66(11), 1997, pp. 2149-2156
The thermal degradation of poly(methyl methacrylate) (PMMA) in the pre
sence of polysulfide polymers, namely, poly( styrene disulfide) (PSD)
and poly(styrene tetrasulfide) (PST) was studied using thermogravimetr
y (TG) and direct pyrolysis-mass spectrometric (DP-MS) analysis. Both
PSD and PST were found to stabilizethe PMMA degradation, which was exp
lained by both radical recombination and a chain-transfer mechanism. (
C) 1997 John Wiley & Sons, Inc.