Zy. Lu et al., A 4-COMPONENT MODEL FOR VOLUME PHASE-TRANSITION, Journal of macromolecular science. Pure and applied chemistry, A34(11), 1997, pp. 2371-2378
By means of the Flory-Huggins and Iwatsubo theory for macro-molecules,
a four-component model of a hydrogel, which consists of a copolymer n
etwork and a solution with two solvents, is given for discussing the '
'normal pattern'' volume phase transition which was proposed by Kataya
ma. Furthermore, the theoretical result shows that an ionic gel can al
so undergo a volume phase transition caused by the variation of the ra
tio of the two components in the copolymer network.